Annie Williams was the daughter of Sally and Emanuel Williams and the sister of Jones Williams, Walter Watkin Williams, Carter Williams, Biddy Ann Williams-Christian, Keziah Williams-Cross, and Isaac Williams. Family relationships are detailed in several Freedmans Bank records for accounts opened by Walter Williams. The most extensive listing is in the record dated 08 AUG 1871. In the record Annie is described as the wife of John Carter of New Kent County, VA.